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BH2Cl
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Boron and Chlorine |
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Nuclear
Quadrupole Coupling Constants |
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in Chloroborane |
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Table 1. Boron and Chlorine nqcc's
in BH2Cl (MHz). |
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Calc. |
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Expt. [1] |
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11B |
Xaa |
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1.005 |
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Xbb |
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3.631 |
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Xcc |
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4.637 |
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10B |
Xaa |
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2.085 |
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Xbb |
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7.531 |
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Xcc |
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9.616 |
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35Cl |
Xaa |
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33.60 |
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34.0(30) |
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Xbb |
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36.12 |
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35.7(20) |
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Xcc |
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- 2.52 |
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- 1.7(30) |
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37Cl |
Xaa |
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26.48 |
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Xbb |
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28.47 |
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Xcc |
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- 1.99 |
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Table 2. Molecular structure parameters, re [2] (Å
and degrees). |
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BH |
1.1834 |
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BCl |
1.7337 |
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HBH |
124.04 |
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[1] Y.Kawashima, H.Takeo, M.Sugie, and C.Matsumura, J.Chem.Phys.
99,820(1993). |
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[2] M.Oswald, J.Flügge, and P.Botschwina, J.Mol.Struct. 320,227(1994). |
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BHCl2 |
BCl3 |
BF2Cl |
BFCl2 |
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BF3 |
BF2H |
BFH2 |
BH3 |
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Table of Contents |
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Molecules/Boron |
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Molecules/Chlorine |
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Summary/Boranes Boron
nqcc's in the fluorochloroboranes. |
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BH2Cl.html |
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Last
Modified 30 Oct 2008 |
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