|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
ClBO |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Boron and Chlorine |
|
|
|
Nuclear
Quadrupole Coupling Constants |
|
|
|
in Chlorine Oxoborane |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
| |
|
|
|
|
|
|
|
|
Table 1. Boron and Chlorine nqcc's in ClBO (MHz). |
|
| |
|
|
|
|
|
|
|
|
|
|
|
Calc. |
|
Expt. [1] |
|
| |
|
|
|
|
|
|
|
|
11B
|
Xzz |
- |
2.489 |
- |
2.5994(33) |
|
|
|
|
|
|
|
|
|
|
10B |
Xzz |
- |
5.161 |
- |
5.4168(49) |
|
|
|
|
|
|
|
|
|
|
35Cl |
Xzz |
- |
48.23 |
- |
48.3656(19) |
|
|
|
|
|
|
|
|
|
|
37Cl |
Xzz |
- |
38.01 |
- |
38.1168(20) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
| |
|
|
|
|
|
|
|
|
|
|
Molecular Structure, rs [2] |
ClB = 1.68274 Å
|
|
|
|
|
|
|
BO = 1.20622 Å |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
[1] B.Gatehouse, H.S.P.Müller, and M.C.L. Gerry, J.Mol.Spectrosc.
190,157 (1998). The nqcc's given above are averages of those given
in this paper for the different isotopic species. |
|
|
[2] K.Kawaguchi, Y.Endo, and E.Hirota, J.Mol.Spectrosc. 93,381 (1982). |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
HBO |
FBO |
BrBO |
HBS |
|
|
FBS
|
ClBS |
BrBS |
CH3BS |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Table of Contents |
|
|
|
|
|
Molecules/Boron |
|
|
|
|
|
Molecules/Chlorine |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
ClBO.html |
|
|
|
|
|
|
Last
Modified 27 Oct 2008 |
|
|
|
|
|
|
|
|
|
|