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GaCl |
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Chlorine and Gallium |
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Nuclear
Quadrupole Coupling Constants |
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in Gallium Monochloride |
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Table 1. Chlorine and Gallium nqcc's (eQqo) in GaCl (MHz). |
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Calc. |
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Expt. [1] |
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35Cl |
eQq |
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12.18 |
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13.30(13) |
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37Cl |
eQq |
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- 9.60 |
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10.54(10) |
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69Ga |
eQq |
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92.30 |
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92.10(14) |
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71Ga |
eQq |
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58.16 |
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57.97(10) |
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The difference between calculated and experimental 35Cl nqcc's is 1.12 MHz (8.4 %). In AlCl,
the difference is 9.2 %. In BCl, the difference is 0.63 %. |
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Bond
Length, re = 2.2017159 Å [2] |
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[1] E.Tiemann, M.Grashoff, and J.Hoeft, Z.Naturforsch. 27a,753(1972). |
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[2] F.J.Lovas and E.Tiemann, J.Phys.Chem.Ref.Data
3,609(1974). |
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GaF |
GaCN |
BCl |
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GaBr |
GaNC |
AlCl |
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Table of Contents |
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Molecules/Gallium |
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Molecules/Chlorine |
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GaCl.html |
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Last
Modified 5 Dec 2003 |
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