LiCH3







 









Lithium


Nuclear Quadrupole Coupling Constants


in Lithium Monomethyl


 








 


 





  








   







Table 1. Lithium nqcc's in LiCH3 (MHz).  Calculation was made on the equilibrium molecular structure [1].
   










Calc.
Expt.
   







7Li eQq
0.3915

 


 







 
Table 2.  Lithium Monomethyl.  Molecular Structure [1,2] (Å and degrees).
 
   re [1] ro [2]
LiC 1.9622(34) 1.959
CH 1.0958(14) 1.111
HCH 105.69(24) 106.2
 

 








[1] J.Breidung and W.Thiel, J.Mol.Struct. 599,239(2001).
[2] M.D.Allean, T.C.Pesch, J.S.Robinson, A.J.Apponi, D.B.Grotjahn, and L.M.Ziurys, Chem.Phys.Lett. 293,397(1998).
 
 
LiH LiF LiCl LiBr
LiNC Li2 LiBH4
NaOH KOH

 








 








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Last Modified 1 May 2006