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OCl X2Pi
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Chlorine |
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Nuclear
Quadrupole Coupling Constants |
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in
Oxygen Monochloride Radical |
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Table 1. Chlorine nqcc's
in OCl (MHz). |
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Calc. |
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Expt. [1] |
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35Cl |
eQq1 |
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- 88.17 |
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- 87.95(19) |
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eQq2 |
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118.48
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126.4(65)
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37Cl |
eQq1 |
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- 69.48 |
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- 69.50(34) |
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eQq1 = Xzz and eQq2 = 2(Xyy-Xxx) [2]
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Bond Length, re =
1.56959 Å [1]. |
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[1] R.K.Kakar, E.A.Cohen, and
M.Geller, J.Mol.Spectrosc. 70,243(1978). |
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[2] L.Cheng, J.Chem.Phys. 143,064301(2015).
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B.J.Drouin, C.E.Miller, E.A.Cohen,
G.Wagner, and M.Birk, J.Mol.Spectrosc. 207,4(2001): For 35Cl, eQq1 = -87.691(81) MHz, eQq2 = -117.71(221) MHz.
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T.Amano, S.Saito, E.Hirota, Y.Morino,
D.R.Johnson, and F.X.Powell, J.Mol.Spectrosc. 30,275(1969). re
= 1.569(1) Å. |
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T.Amano, E.Hirota, and Y.Morino,
J.Mol.Spectrosc. 27,257(1968). re = 1.569(4) Å. |
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CCl | NCl |
SiCl | NO
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OBr
| OI
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Table of Contents |
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Molecules/Chlorine |
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OCl.html |
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Last
Modified 3 June 2003 |
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