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SF5Br |
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Bromine |
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Nuclear
Quadrupole Coupling Constants |
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in Thiopentafluorobromide |
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Table 1. Bromine nqcc's in SF5Br (MHz). |
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Calc. |
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Expt. [1] |
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79Br |
Xzz |
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764.0 |
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708(12) |
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81Br |
Xzz |
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638.3 |
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585(8) |
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The difference between calculated and experimental 79Br
nqcc's is 56 MHz (7.9 %); and for 81Br, 43
MHz (7.4 %). |
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Table 2. Structure parameters
[1] (Å and degrees). |
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SBr |
2.133(5) |
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SFeq |
1.646(10) |
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SFax |
1.51(3) |
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FaxSFeq |
83.4(5) |
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[1] R.Jurek, P.Goulet, C.Verry, and A.Poinsot,
Can.J.Phys. 61,1405(1983). |
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SF5Cl |
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Table of Contents |
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Molecules/Bromine |
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SF5Br.html |
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Last
Modified 28 Jan 2005 |
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