SF5Br







 









Bromine


Nuclear Quadrupole Coupling Constants


in Thiopentafluorobromide


 








 

 
 





 








   







Table 1. Bromine nqcc's in SF5Br (MHz).
   










Calc.
Expt. [1]
   





79Br Xzz
764.0
708(12)
 
81Br Xzz
638.3
585(8)
 


 







The difference between calculated and experimental 79Br nqcc's is 56 MHz (7.9 %); and for 81Br, 43 MHz (7.4 %).
   

 
Table 2. Structure parameters [1] (Å and degrees).
SBr 2.133(5)
SFeq 1.646(10)
SFax 1.51(3)
FaxSFeq 83.4(5)

 

 








[1] R.Jurek, P.Goulet, C.Verry, and A.Poinsot, Can.J.Phys. 61,1405(1983).
 
 

SF5Cl
 

 








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Molecules/Bromine

 













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Last Modified 28 Jan 2005