CCAs





 









Arsenic


Nuclear Quadrupole Coupling Constants


in Arsenic Dicarbide Radical


 











 





 








 







Table 1. 75As nqcc's in Arsenic Dicarbide (MHz).  Calculation was made on the ro, rs and rm(1) structures of Sun et al. [1]
 










Calc / Structure
Expt. [1]
 







75As eQq - 216.6 / ro - 201.790(20)
- 213.4 / rs
- 211.3 / rm(1)

 





 







 

Table 2. Arsenic Dicarbide Structure Parameters (Å) [1]
 
    ro     rs   rm(1)
CC 1.2884(48) 1.2851(4) 1.2872(3)
CAs 1.7362(33) 1.7427(5) 1.7455(5)



 








 








[1] M.Sun, D.J.Clouthier, and L.M.Ziurys, J.Chem.Phys. 131,224317(2009).


 








 








AsCl3 AsD3 AsH2 Vinylarsine

 







 








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Last Modified 29 Oct 2012