NBr Triplet






 









Bromine


Nuclear Quadrupole Coupling Constants


in Nitrogen Monobromide Radical


 








 

 
 





  








   







Table 1. Bromine nqcc's in NBr (MHz).
   










Calc.
Expt. [1]
   






79Br eQq - 491.7 - 505.9(57)

 






81Br eQq - 410.8 -
428.6(50)

 







 







  Difference between calculated and experimental 79Br nqcc's is 14.2 MHz (2.8 %).  For 81Br, the difference is 17.8 MHz (4.2 %).

 








 








Bond Length, r= 1.77799(11) Å [1].

 








 








[1] T.Sakamaki, T.Okabayashi, and M.Tanimoto, J.Chem.Phys. 109,7169(1998).

 








 








NCl OCl SiCl NO

CCl CN NS


 








 








Table of Contents




Molecules/Bromine




 








 













NBr.html






Last Modified 12 Sept 2003