OBr X2Pi





 









Bromine


Nuclear Quadrupole Coupling Constants


in Oxygen Monobromide Radical


 








 

 
 





  








   







Table 1.  Bromine nqcc's in OBr (MHz).
   










Calc.
Expt. [1]
   






79Br eQq1
658.60
658.676(83)


  eQq2
814.70

862.48(47)










81Br eQq1
550.24



 







 








eQq1 = Xzz and eQq2 = 2(Xyy-Xxx) [2]


 









 








Bond Length, r= 1.7172(25) Å [3].

 








 








[1] B.J.Drouin, C.E.Miller, H.S.P.Müller, and E.A.Cohen, J.Mol.Spectrosc. 205,128(2001).


[2] L.Cheng, J.Chem.Phys. 143,064301(2015).

[3] F.J.Lovas and E.Tiemann, J.Phys.Chem. Ref.Data 3,609(1974).


 








T.Amano, A.Yoshinago, and E.Hirota, J.Mol.Spectrosc. 44,594(1972): r= 1.7171(13) Å

 









 








OCl OI



 








 








Table of Contents




Molecules/Bromine




 








 













OBr.html






Last Modified 6 Dec 2012