SiH3I


























 









Iodine


Nuclear Quadrupole Coupling Constants


in Silyl Iodide



 








 

 
 





 








   







Table 1. Iodine eQq in SiH3I (MHz).  Calculation was made on rs [1] and ro [2] structures.

   










Calc.
Expt. [1]
   






127I eQq - 1262.2  [1]
- 1245.1



-
1265.0  [2]




 








 







   












Table 2.  Structure parameters, rs [1] (Å and degrees).


rs [1] ro [2]





SiI 2.437
2.43835(59)

SiH 1.485
1.47414(142)

HSiI 107.8
108.157(166)


 








 








[1] R.Kewley, P.M.McKinney, and A.G.Robiette, J.Mol.Spectrosc. 34,390(1970).


[2] J.L.Duncan, J.L.Harvie, and D.C.McKean, J.Mol.Struct. 145,225(1986).


 









 








CH3I SiF3I (CH3)3SiI
CH3SiH2I


 








 








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Molecules/Iodine




 













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Last Modified 23 April 2015