|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SiH3I |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Iodine |
|
|
|
Nuclear
Quadrupole Coupling Constants |
|
|
|
in Silyl Iodide
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Table 1. Iodine eQq
in SiH3I (MHz). Calculation was made on rs [1] and ro [2] structures.
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Calc. |
|
Expt. [1] |
|
|
|
|
|
|
|
|
|
|
127I |
eQq |
- |
1262.2 [1]
|
- |
1245.1 |
|
|
|
|
-
|
1265.0 [2]
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Table 2. Structure
parameters, rs [1] (Å and degrees). |
|
|
rs [1]
|
ro [2]
|
|
|
|
|
|
SiI
|
2.437
|
2.43835(59) |
|
SiH
|
1.485
|
1.47414(142) |
|
HSiI
|
107.8
|
108.157(166) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
[1] R.Kewley, P.M.McKinney, and A.G.Robiette, J.Mol.Spectrosc. 34,390(1970).
|
|
|
[2] J.L.Duncan, J.L.Harvie, and D.C.McKean, J.Mol.Struct. 145,225(1986).
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
CH3I |
SiF3I |
(CH3)3SiI
|
CH3SiH2I
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Table of Contents |
|
|
|
|
|
Molecules/Iodine |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SiH3I.html |
|
|
|
|
|
|
Last
Modified 23 April 2015 |
|
|
|
|
|
|
|
|
|
|