FNO
	Nitrogen
	Nuclear Quadrupole Coupling Constants
		in Nitrosyl Fluoride
	Table 1.  Nitrogen nqcc's in FNO (MHz).  Calculation was made on the structure of Esposti et al. [2].     Calc. Expt. [1]     14N Xaa 1.634 1.7343(9) Xbb - 5.035 - 5.0407(8) Xcc 3.401 3.3064(8) |Xab| 3.062   RMS 0.080 (2.4 %) RSD 0.030 (1.3 %)
	Table 2. Molecular structure parameters, re [2] (Å and degrees).   FN 1.51658(25) NO 1.13155(23) FNO 109.9220(72)
	[1] C.Styger, B.Gatehouse, N.Heineking, W.Jäger, and M.C.L.Gerry, J.Chem.Soc. Faraday Trans. 89,1899(1993).
	[2] C.Delgi Esposti, G.Cazzoli, and P.G.Favero, J.Mol.Spectrosc. 109,229(1985); G.Cazzoli, C.Delgi Esposti, P.G.Favero, and P.Palmieri, Nuovo Cimento 3,627(1984).
	F.Rohwer and A.Guarnieri, Z.Naturforsch. 35a,336(1980).  Xaa = 1.73(19) MHz, Xbb = -5.02(18) MHz, Xcc = 3.29(18) MHz.
	K.S.Buckton, A.C.Legon, and D.J.Millen, Trans. Faraday Soc. 65,1975(1969).  Xaa = 1.69(5) MHz, Xbb = -4.83(5) MHz, Xcc = 3.14(5) MHz.
	"Theoretical study of 14N quadrupole coupling constants in ... FNO"  R.Polák and J.Fišer, Chemical Physics 351,83(2008).
	"The Case of the Weak N-X Bond: Ab Initio, Semi-Experimental, and Experimental Equilibrium Structures of XNO (X = H, F, Cl, OH) and FNO2"  J.Demaison, A.G.Császár, and A.Dehayem-Kamadjeu, J.Phys.Chem A, 110,13609(2006).
	HNO		ClNO		BrNO		FNO2
	Table of Contents
	Molecules/Nitrogen
						FNO.html
						Last Modified 30 March 2013