NH2OH
 

 








Nitrogen


Nuclear Quadrupole Coupling Constants


in Hydroxylamine


 







 
 
   







Table 1.  Nitrogen nqcc's in NH2OH (MHz).  Calculation was made on the ro structure of Tsunekawa [1].
   










Calc.
Expt. [1]
   






14N Xaa 5.693 5.67(10)
Xcc - Xbb 6.232 5.64(28)
Xbb 0.270 - 0.02
Xcc - 5.963 - 5.66
|Xac| 1.219
 
 
Calculated and experimental Xaa agree to within the uncertainty in the experimental value.  For (Xbb - Xcc) however, the difference between calculated and experimental is 0.59 MHz (10 %).
 
 
Table 2. Molecular structure parameters, ro [1] (Å and degrees).
 
NH 1.016
Z-Matrix NO 1.453
OH 0.962
HNH 107.10
HNO 103.25
NOH 101.37
 
 
[1] S.Tsunekawa, J.Phys.Soc.Jpn. 33,167(1972).

 








 








H2NCHO H2NCHS NH2Cl NH2F
BH2NH2 BF2NH2 PF2NH2 B2H5NH2
NH2SH
 

 








Table of Contents



Molecules/Nitrogen
 

 













NH2OH.html






Last Modified 23 May 2003