BH2Cl




 

 









Boron and Chlorine


Nuclear Quadrupole Coupling Constants


in Chloroborane


 







 

 








   







Table 1. Boron and Chlorine nqcc's in BH2Cl (MHz).
   










Calc.
Expt. [1]
   






11B Xaa - 1.005
Xbb - 3.631
Xcc 4.637
 
10B Xaa - 2.085
Xbb - 7.531
  Xcc 9.616
 
35Cl Xaa - 33.60 - 34.0(30)
Xbb 36.12 35.7(20)
  Xcc - 2.52 - 1.7(30)
 
37Cl Xaa - 26.48
Xbb 28.47
Xcc - 1.99
 


 







 
 
Table 2. Molecular structure parameters, re [2] (Å and degrees).
BH 1.1834
BCl 1.7337
HBH 124.04


 
 

[1] Y.Kawashima, H.Takeo, M.Sugie, and C.Matsumura, J.Chem.Phys. 99,820(1993).
[2] M.Oswald, J.Flügge, and P.Botschwina, J.Mol.Struct. 320,227(1994).

 








 








BHCl2 BCl3 BF2Cl BFCl2
BF3 BF2H BFH2 BH3
 

 








Table of Contents



Molecules/Boron

Molecules/Chlorine



Summary/Boranes   Boron nqcc's in the fluorochloroboranes.
 

 













BH2Cl.html






Last Modified 30 Oct 2008