BHCl2							PDF
		Boron and Chlorine
	Nuclear Quadrupole Coupling Constants
		in Dichloroborane
	Table 1. Boron nqcc's in BHCl2 (MHz).     Calc. Expt. [1]     11B Xaa - 0.682 0.4(10) Xbb - 2.838 - 3.3(5) Xcc 3.520 2.9(11)   10B Xaa - 1.413 Xbb - 5.886   Xcc 7.299
	Table 2. Chlorine nqcc's in BHCl2 (MHz).     Calc. Expt. [1]     35Cl Xaa - 20.99 - 21.4(10) Xbb 16.76 16.4(5) Xcc   4.23   5.0 Xab ± 30.00   Xxx 33.33 Xyy   4.23 Xzz - 37.56 ETA - 0.775 Øz,a 28.9 Øa,BCl 29.8 Øz,BCl   0.9   37Cl Xaa - 16.54 Xbb 13.21 Xcc   3.33 Xab ± 23.65
	The angle between the two z-axes is 1.8o larger than the ClBCl angle.  This is typical of  the XCl2 dichloride moiety.
	Table 2. Molecular structure parameters, rs [1] (Å and degrees). BH 1.184 BCl 1.735 ClBCl 120.4
	[1] M.Sugie, H.Takeo, and C.Matsumura, Spectrochimica Acta 50A, 1379(1994).
	BH2Cl		BCl3		BF2Cl		BFCl2
	BF3		BF2H		BFH2		BH3
	CH3BCl2		OCl2		SCl2		CH2CCl2
	OCCl2		CH2Cl2		SCCl2
	Table of Contents
	Molecules/Boron
	Molecules/Chlorine
	Summary/Boranes   Boron nqcc's in the fluorochloroboranes.
						BHCl2.html
						Last Modified 30 Oct 2008