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GeH3Cl |
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Chlorine and Germanium |
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Nuclear
Quadrupole Coupling Constants |
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in Germyl Chloride |
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Table 1. Chlorine and Germanium nqcc's in GeH3Cl (MHz). |
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Calc. |
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Expt. [1] |
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35Cl |
Xzz |
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46.82 |
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46.9500(26) |
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37Cl |
Xzz |
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36.90 |
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37.0004(25) |
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73Ge |
Xzz |
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92.47 * |
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93.032(15) |
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91.93 ** |
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* B3P86/6-311G(2d) |
** B3PW91/6-311G(2d) |
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| Table 2. Molecular structure parameters, re
[2] (Ċ and degrees). |
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GeCl |
2. 14470 |
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GeH |
1.51559 |
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HGeCl |
107.107 |
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[1] G.Wlodarczak, N.Heineking, and H.Dreizler, J.Mol.Spectrosc. 147,252(1991). |
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[2] J.Demaison, G.Wlodarczak, J.Burie, and
H.Bürger, J.Mol.Spectrosc. 140,322(1990). |
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GeH3F |
GeH3Br |
GeH3CN |
GeH3CH3 |
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CH3Cl |
GeF3Cl |
SiH3Cl |
GeH3CCH |
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Table of Contents |
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Molecules/Chlorine |
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Molecules/Germanium |
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GeH3Cl.html |
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Last
Modified 7 Oct 2004 |
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