GeH3Br







 









Germanium and Bromine


Nuclear Quadrupole Coupling Constants


in Germyl Bromide


 








 

 
 





 








   







Table 1. Germanium and Bromine nqcc's in GeH3Br (MHz).
   










Calc.
Expt. [1]
 
73Ge Xzz - 89.72 *
- 89.22 **
   





79Br Xzz
378.89
384(2)
 
81Br Xzz
316.55
321(3)
 


 







* B3P86/6-311G(2d) ** B3PW91/6-311G(2d)
   

 
Table 2. Structure parameters, rs [2] (Å and degrees).
GeBr 2.297
GeH 1.527
HGeBr 106.2

 

 








[1] S.N.Wolf and L.C.Krisher, J.Chem.Phys. 56,1040(1972).
[2] J.R.Durig, A.B.Mohamad, P.L.Trowell, and Y.S.Li, J.Chem.Phys. 75, 2147(1981).
 
 

GeH3F GeH3Cl GeH3CN GeH3CH3

CH3Br SiH3Br CF3Br GeH3CCH
 

 








Table of Contents



Molecules/Germanium
Molecules/Bromine
 

 













GeH3Br.html






Last Modified 7 Oct 2004