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GeH3Br |
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Germanium and Bromine |
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Nuclear
Quadrupole Coupling Constants |
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in Germyl Bromide |
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Table 1. Germanium and Bromine nqcc's in GeH3Br (MHz). |
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Calc. |
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Expt. [1] |
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73Ge |
Xzz |
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89.72 * |
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89.22 ** |
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79Br |
Xzz |
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378.89 |
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384(2) |
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81Br |
Xzz |
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316.55 |
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321(3) |
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* B3P86/6-311G(2d) |
** B3PW91/6-311G(2d) |
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Table 2. Structure parameters, rs
[2] (Å and degrees). |
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GeBr |
2.297 |
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GeH |
1.527 |
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HGeBr |
106.2 |
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[1] S.N.Wolf and L.C.Krisher, J.Chem.Phys. 56,1040(1972). |
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[2] J.R.Durig, A.B.Mohamad, P.L.Trowell, and
Y.S.Li, J.Chem.Phys. 75, 2147(1981). |
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GeH3F |
GeH3Cl |
GeH3CN |
GeH3CH3 |
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CH3Br |
SiH3Br |
CF3Br |
GeH3CCH |
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Table of Contents |
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Molecules/Germanium |
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Molecules/Bromine |
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GeH3Br.html |
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Last
Modified 7 Oct 2004 |
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