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CH3GeH3
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Germanium |
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Nuclear
Quadrupole Coupling Constants |
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in Methyl Germane |
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Table 1. 73Ge
nqcc's in CH3GeH3 (MHz). |
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Calc. [a] B3P86/6-311G(2d) model. |
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Calc. [b] B3PW91 /6-311G(2d) model. |
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Calc. [a]
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Calc. [b] |
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Expt. [1] |
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Xzz |
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2.41 |
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2.58 |
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+ 3 |
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Table 2. Molecular structure parameters, ro
[1] (Å and degrees). |
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GeC |
1.9453 |
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GeH |
1.529 |
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CH |
1.083 |
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HGeH |
109.25 |
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HCH |
108.42 |
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[1] V.W.Laurie, J.Chem.Phys. 30,1210(1959). " .... the hyperfine
structure ... was barely detectable with the available resolution." |
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GeH3Cl |
GeH3Br |
GeH3CN |
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GeH3F |
GeH3CCH |
GeH2FCH3 |
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Table of Contents |
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Molecules/Germanium |
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GeH3CH3.html |
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Last
Modified 7 Oct 2004 |
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