CH3GeH3







 









Germanium


Nuclear Quadrupole Coupling Constants


in Methyl Germane


 








 


 





  








   







Table 1. 73Ge nqcc's in CH3GeH3 (MHz).
   






Calc. [a] B3P86/6-311G(2d) model.
Calc. [b] B3PW91 /6-311G(2d) model.
 


Calc. [a]

Calc. [b]
Expt. [1]
   







Xzz 2.41 2.58    + 3
 


 







 
Table 2. Molecular structure parameters, ro [1] (Å and degrees).
GeC 1.9453
GeH 1.529
CH 1.083
HGeH 109.25
HCH 108.42

 








 








[1] V.W.Laurie, J.Chem.Phys. 30,1210(1959).  " .... the hyperfine structure ... was barely detectable with the available resolution."
 
 
GeH3Cl GeH3Br GeH3CN
GeH3F GeH3CCH GeH2FCH3
 

 








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Last Modified 7 Oct 2004