GeH3F







 









Germanium


Nuclear Quadrupole Coupling Constants


in Germyl Fluoride


 








 


 





  








   







Table 1. 73Ge nqcc's in GeH3F (MHz).
   






Calc. [a] B3P86/6-311G(2d) model.
Calc. [b] B3PW91 /6-311G(2d) model.
 


Calc. [a]

Calc. [b]
Expt. [1]
   







Xzz - 92.78 - 92.20 - 93.03(10)
 


 







 
 
Table 2. Molecular structure parameters, re [2] (Å and degrees).
GeF 1.730945
GeH 1.51451
HGeF 106.073

 








 








[1] L.C.Krisher, J.A.Morrison and W.A.Watson, J.Chem.Phys. 57,1357 (1972).
[2] M.LeGuennec, W.Chen, G.Wlodarczak, and J.Demaison, J.Mol. Spectrosc. 150,493(1991).
 
 
GeH3Cl GeH3Br GeH3CN
GeH3CH3 GeH3CCH
 

 








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Molecules/Germanium

 








 













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Last Modified 7 Oct 2004